Glosaurus
Chemical Elements

Protactinium

Pa 91

A rare and fascinating actinide element.
Protactinium is a chemical element with the symbol Pa and atomic number 91. It is part of the actinide series and is found in trace amounts in uranium ores. Protactinium is notable for being a precursor to the fissile isotope uranium-233, making it of interest in nuclear research.
Symbol
Pa
Atomic number
91
Atomic mass
231.03588
Classification
Actinides
Melting point
1572°C
Boiling point
4000°C
State of matter
Solid
Appearance
Silvery metallic
Discovery and history
Protactinium was first discovered in 1913 by German chemist Otto Hahn and his colleague Lise Meitner, who identified it while studying uranium in a radioactive decay chain. However, it wasn't until 1949 that the element was officially named protactinium. The name is derived from the Greek word 'pro' meaning 'before,' referring to its position in the decay series leading to uranium-233. Initially, the element was difficult to isolate due to its scarcity and the complexity of its chemistry. Over the years, advancements in separation techniques and the increasing interest in nuclear processes have spurred further research into protactinium and its isotopes.
Natural occurrence
Protactinium is found in nature in trace amounts, primarily in uranium ores such as uraninite and pitchblende. It is produced through the decay of uranium-235 and uranium-238. The natural occurrence of protactinium is extremely low, typically around 0.034 parts per million (ppm) in the Earth's crust. Its most stable isotope, protactinium-231, has a half-life of approximately 32,760 years, contributing to its presence in irradiated uranium. Beyond natural deposits, protactinium has also been synthesized during nuclear reactions and is researched in laboratories for its potential applications.
Biological role and importance
Currently, there is limited research on the biological role of protactinium. It is not known to play any essential role in biological systems, and exposure to it can be hazardous due to its radioactivity. As an actinide, protactinium can pose health risks if ingested or inhaled. The element can accumulate in bones and internal organs, leading to potential radiological hazards. Consequently, the handling of protactinium is strictly controlled in laboratory settings to prevent radiation exposure. While it does not have a biological role, its isotopes are of interest for their potential utility in nuclear technology, particularly in the development of nuclear fuels.
Physical and chemical properties
Protactinium is a dense, silvery-gray metal that is characterized by its radioactivity and high melting point of approximately 1,200 degrees Celsius. It has a relatively high density, around 15.4 grams per cubic centimeter, which is comparable to other actinides. Chemically, protactinium is classified as a member of the actinide series, exhibiting oxidation states primarily of +4 and +5. Its chemical behavior resembles that of thorium and uranium, forming various compounds, including oxides and halides. Protactinium is stable in air at room temperature but tends to form oxides when exposed to oxygen, demonstrating reactivity similar to other transition metals.
Uses and applications
Historically, protactinium has been investigated for potential use in nuclear reactors and as a component of nuclear fuel cycles. Its isotope, protactinium-233, can be bred from thorium-232, and it has potential as a fissile material in nuclear reactors. However, due to its scarcity and the challenges associated with its handling, protactinium has not found widespread commercial applications. Research in radiochemistry and nuclear physics continues to explore protactinium's properties and its potential utility in advanced reactor designs and as part of nuclear waste management strategies. Furthermore, its role in understanding the behavior of radioactive materials contributes valuable insights into both nuclear energy and environmental safety.
Did you know?
  • Protactinium was one of the first elements discovered through the study of radioactivity.
  • The element is highly radioactive, and its isotopes are used in research rather than commercial applications.
  • Protactinium's name reflects its position in relation to uranium, as it is a precursor to fissile isotopes.
  • Because of its radioactivity, protactinium glows faintly in the dark.
  • Only small quantities of protactinium are produced naturally, making it one of the rarest elements on Earth.