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Chemical Elements

Polonium

Po 84

A highly radioactive metalloid.
Polonium is a chemical element with the symbol Po and atomic number 84. It is a rare and highly radioactive metalloid that occurs in trace quantities and is known for its intense radioactivity, which poses significant health risks. Polonium is classified as a chalcogen in group 16 of the periodic table.
Symbol
Po
Atomic number
84
Atomic mass
209
Classification
Metalloids
Melting point
254°C
Boiling point
962°C
State of matter
Solid
Appearance
Silvery-grey and metallic
Discovery and history
Polonium was discovered in 1940 by the prominent chemists Marie Curie and her husband Pierre Curie, along with a fellow scientist, Frederic Joliot-Curie. Their research aimed to explore the properties of radioactive elements, focusing primarily on the new radioactivity phenomenon. The element was named 'polonium' in honor of Poland, Curie's homeland, as a symbol of her support for her country, which was facing political challenges at the time. The discovery occurred during the Curies' investigations into the extraction of radioactive isotopes from uranium ore, which highlighted the existence of polonium as a decay product of heavier elements. Following its discovery, polonium's properties and potential applications have been studied extensively, and it has since been recognized for its critical role in the field of nuclear science.
Natural occurrence
Polonium is a rare element that exists in trace amounts in the Earth's crust. It is primarily produced through the alpha decay of heavier elements such as uranium and thorium. The estimated abundance of polonium in the Earth's crust is about 0.2 micrograms per ton. It can also be found in very small quantities in pitchblende, a mineral that contains uranium. Because of its rarity, polonium is not commonly extracted from the environment and is usually synthesized in nuclear reactors or produced through the decay of other radioactive materials. Its pronounced radioactivity makes it challenging to collect and study in natural settings, which further contributes to its status as a seldom-concentrated element within nature.
Biological role and importance
Polonium does not have a recognized biological role in living organisms. Its extreme radioactivity and hazardous properties pose significant health risks. Exposure to polonium can lead to serious biological effects, including cellular mutation and increased cancer risk due to the ionizing radiation it emits. While some stable isotopes of other elements are essential for life, polonium is not one of them and, instead, is typically considered toxic and lethal. Its presence within biological systems is accidental and generally undesirable, making it crucial to minimize exposure in all settings.
Physical and chemical properties
Polonium is a metalloid with some distinct physical and chemical properties. It is a gray, metallic element with a density of approximately 9.2 grams per cubic centimeter. Polonium is solid at room temperature and possesses a melting point of about 254 °C and a boiling point of approximately 962 °C. This element exhibits a crystalline structure with a face-centered cubic crystal lattice. Chemically, polonium is reactive, especially with oxygen, forming polonium dioxide (PoO2) when oxidized. Additionally, polonium easily undergoes alpha decay, emitting alpha particles, which classify it as a highly radioactive substance. Polonium's isotopes, especially polonium-210, are highly studied due to their unique radioactive properties.
Uses and applications
Despite its radioactivity and toxicity, polonium has niche applications, particularly in scientific research and technology. Polonium-210 is utilized as a heat source in space applications, such as in radioisotope thermoelectric generators that power spacecraft by converting heat released from its radioactive decay into electricity. Additionally, polonium is employed in some types of anti-static devices, primarily in industrial applications to eliminate static charges on plastic and other materials. Research continues into additional potential uses of polonium in various fields, although its dangerous properties necessitate strict safety protocols in any application.
Did you know?
  • Polonium was the first element discovered by the Curies, who were pioneers in radioactivity research.
  • Polonium-210 is approximately 250,000 times more toxic than cyanide.
  • Polonium is used in some types of smoke detectors as an ionization source to detect smoke particles.
  • The element name 'polonium' was suggested by its discoverers to honor the then-occupied Poland.
  • Alpha radiation from polonium requires only a piece of paper to block it, but it can be extremely damaging if ingested.