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Chemical Elements

Promethium

Pm 61

A rare and radioactive lanthanide.
Promethium is a chemical element with the symbol Pm and atomic number 61. It is part of the lanthanide series, a group of 15 elements within the f-block of the periodic table. Notably, promethium is one of the few elements that does not have stable isotopes, making it radioactive and relatively rare in nature.
Symbol
Pm
Atomic number
61
Atomic mass
145
Classification
Lanthanides
Melting point
1042°C
Boiling point
3000°C
State of matter
Solid
Appearance
Silvery-white metal
Discovery and history
Promethium was discovered in 1945 by a team of American chemists, including Charles D. Coryell, J. A. Marinsky, and Glenn T. Seaborg, at Oak Ridge National Laboratory. The discovery followed the extraction of uranium from the fission products of uranium, which were characterized using chemical methods. Promethium was named after Prometheus, the Greek mythological figure who stole fire from the gods and gave it to humanity. The element was initially obtained as a result of experiments on the fission of uranium isotopes during World War II, underscoring its significance during this transformative period in science and technology. Its radioactive properties were studied extensively, leading to applications in various fields, although the challenges related to its rarity limited widespread use.
Natural occurrence
Promethium does not occur naturally in significant quantities on Earth due to its radioactive nature and relatively short half-life of its isotopes. It is primarily formed in trace amounts from the decay of uranium and thorium over long geological timeframes. However, the most notable sources of promethium are as a byproduct in nuclear reactors and from the fission of uranium. In nature, it has been detected in small quantities in ores and is more commonly found in the remnants of spent fuel from nuclear reactors, making it very rare and necessitating the production of this element in laboratories for most practical applications.
Biological role and importance
Promethium plays a negligible role in biological systems, primarily due to its high radioactivity and rarity. It is not considered to have any essential function in living organisms, nor has it been observed to participate in any biochemical processes. Nevertheless, understanding the element contributes to the overall knowledge of lanthanides and their potential effects on health and the environment, particularly regarding safety and radiation exposure in medical or industrial contexts.
Physical and chemical properties
Promethium is characterized by its silvery-white metallic appearance, resembling other lanthanides. It has a melting point of approximately 1,045 degrees Celsius and a boiling point estimated to be around 3,000 degrees Celsius. The element is classified as soft and relatively malleable compared to its heavier homologs. Promethium’s chemical properties are akin to those of its lanthanide relatives, forming trivalent ions (Pm^3+) that are stable in most chemical environments. Promethium can react with water and acids, producing hydrogen gas and metal salts, which underlines its typical metallic behavior. Its radioactivity further distinguishes it, as the most prominent isotopes, such as Pm-145, have half-lives of around 17.7 years.
Uses and applications
Despite its rarity, promethium has several practical applications primarily due to its radioactive properties. It is utilized in luminous paint, which is applied to watch dials and aircraft instruments, providing visibility in darkness. Additionally, promethium is used in atomic batteries, which convert radioactive decay into electrical energy, providing power for pacemakers and space probes. Research into utilizing promethium in lightweight batteries and various electronic devices continues, highlighting the element’s potential despite the limited quantities that can be accessed. Moreover, its isotopes are studied in neutron radiography and for potential radioactive thermophotovoltaics.
Did you know?
  • Promethium is the only lanthanide that is not found in nature in a significant quantity.
  • The element was artificially produced shortly after the end of World War II.
  • Due to its radioactivity, promethium glows faintly in the dark, making it visually distinct.
  • Promethium has no stable isotopes and is primarily used in specialized applications.