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Chemical Elements

Bismuth

Bi 83

A heavy metal with unique properties.
Bismuth is a chemical element with the symbol Bi and atomic number 83. It is a brittle metal that displays a variety of interesting properties, including low thermal conductivity and high resistance to corrosion. Bismuth is primarily characterized by its distinct pinkish hue and complex crystal structures, which can exhibit a beautiful array of colors when oxidized.
Symbol
Bi
Atomic number
83
Atomic mass
208.98
Classification
Post-transition metals
Melting point
271°C
Boiling point
1564°C
State of matter
Solid
Appearance
Brittle metal with a lustrous, silver-white appearance and a slight pinkish tinge
Discovery and history
Bismuth has a rich history that dates back to ancient times. Although it has been known since antiquity, it was often confused with lead and tin due to their similar appearances. The name 'bismuth' is believed to be derived from the German word 'Wismut,' which refers to its heavy, white appearance. It wasn't until the 17th century that bismuth was isolated as a distinct element. The first proper identification is attributed to the German chemist, Georg Brandt, in the 1730s, but it was not until 1753 that a detailed description and isolation of bismuth was provided by Claude François Geoffroy, a French chemist. The discovery of the element's unique properties provided pathways for further scientific research and applications in various fields, including medicine and metallurgical processes.
Natural occurrence
Bismuth is relatively rare in nature, typically found in small quantities in various ores of lead, copper, and tin. It is usually obtained as a byproduct during the processing of other metals. Notably, bismuth is predominantly sourced from bismuthinite (Bi2S3), which is its principal mineral. The Earth's crust contains approximately 0.00002% of bismuth, indicating its scarcity. Despite its rarity, bismuth is typically associated with hydrothermal mineral deposits and can often be found in metalliferous veins, where it can co-occur with other base and precious metals.
Biological role and importance
Bismuth’s biological role is somewhat limited compared to other elements; however, it does possess certain health benefits. For instance, bismuth subsalicylate is an important compound used in the treatment of gastrointestinal issues, including diarrhea and stomach upset. Its ability to inhibit the growth of bacteria, including Helicobacter pylori, the bacterium linked to gastric ulcers, further emphasizes its medicinal importance. While bismuth is not considered an essential element for human health, its therapeutic applications have made it a valuable compound in pharmaceuticals.
Physical and chemical properties
Bismuth is a heavy, silvery-white metal with a characteristic pinkish hue in its pure form. It has a relatively low melting point of 271.4 °C and a boiling point of 1,564 °C. One unique aspect of bismuth is its low thermal conductivity, which makes it an excellent alternative to lead in applications requiring low toxicity. Chemically, bismuth is relatively inert, displaying resistance to corrosion and oxidation. It reacts with oxygen at elevated temperatures to form bismuth oxide, a white powder. Additionally, bismuth is known for its high density and low toxicity relative to other heavy metals, which makes it an attractive option for various uses.
Uses and applications
Bismuth is commonly employed in a variety of applications due to its unique properties. One of the most notable uses is in pharmaceuticals, particularly in formulations for treating gastrointestinal disorders, such as Pepto-Bismol. In addition to medicine, bismuth is utilized in the manufacturing of low-melting alloys, which are used in applications such as fire safety devices, as well as in soldering materials due to their non-toxic nature. Moreover, it is also employed in the production of pigments and as a replacement for lead in shot and bullet manufacturing. Furthermore, bismuth's nontoxic attributes make it a viable option in a range of applications across industries, from electronics to cosmetics.
Did you know?
  • Bismuth is the heaviest non-radioactive element known to exist in nature.
  • When bismuth solidifies, it expands, unlike most metals which contract.
  • Bismuth has the lowest thermal conductivity of any metal, making it a good insulator.
  • It is non-toxic, which makes it a safer alternative to lead in many applications.
  • Crystals of bismuth can form iridescent rainbow-colored surfaces, making them visually stunning.